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She is Princess Celestia's younger sister from "My Little Pony: Friendship is Magic".
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Princess Luna played Megara in Godzulles

She secretly works for Hades

Princess Luna played Tim the Minion in Awesome Me (alongside Tigress).

She is a tall Minion.

Princess Luna played Princess Kida in Atlantis: The Lost Empire (Twilight'sSpaceStar17's Animal Style)

Princess Luna played Miss Right in The Secret of NIMH (Twilight'sSpaceStar17's Style)

Princess Luna played Dr. Buttocks in Trixie and the Ghostly Adventures

She is a ghost

Princess Luna played J.A.R.V.I.S in The Beak

She is a artificial intelligence

Princess Luna played Karone in Power Ponies In Space and Power Ponies Lost Galaxy

She is Andros' Sister and the 2nd Pink Galaxy Ranger.

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